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Impact of the Bonding Sites at the Inner or Outer π‑Bridged

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  • 2020-12-10 16:12:13
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ImpactoftheBondingSitesattheInnerorOuterπ‑BridgedPositionsforNon-FullereneAcceptorsShouliMing,†,⊥Cai’eZhang,†,⊥PengchengJiang,†QinglinJiang,∥ZaifeiMa,§JinshengSong,*,‡andZhishanBo*,††BeijingKeyLaboratoryofEnergyConversionandStorageMaterials,CollegeofChemistry,BeijingNormalUniversity,Beijing100875,China‡EngineeringResearchCenterforNanomaterials,HenanUniversity,Kaifeng475004,China§CenterforAdvancedLow-DimensionMaterials,StateKeyLaboratoryforModificationofChemicalFibersandPolymerMaterials,CollegeofMaterialsScienceandEngineering,DonghuaUniversity,Shanghai201620,China∥CollegeofChemistryandMolecularEngineering,QingdaoUniversityofScience&Technology,Qingdao266042,China*SSupportingInformationABSTRACT:TwoA−π−D−π−A-typenon-fullereneaccept-ors(IDT-ToFICandIDT-TiFIC)with5-hexylthienylchainssubstitutedattheinnerandouterβ-positionsofthethiopheneπ-bridgehavebeendesigned,respectively.Impactsofvariedpositionalmodificationsaresystematicallystudied.ByutilizingPBDB-Tasthedonor,polymersolarcellsareconstr

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